Kind of the opposite of the topic, but I recently got a Groovymame / CRTEmuTools setup going on my 27" Trinitron FD Wega TV and let me tell you it works like a charm. Beautiful composite sync 15KHz signal coming from the H-Sync and RGB pins. When I saw and heard some of the late 80's and early 90's classics on this setup I almost had to wipe away a tear.
It just so happened I had one of the most ideal VGA cards for this type of thing given to me, the AMD/ATI HD 5450. Only downside is that CGA games really need to be played in interlace mode to get all the detail (and that works fine, to be sure), but yeah, fantastic. The resolution auto-switching of GroovyMAME + the ability to tweak and lock any one of the 15KHz modes as you see fit is just fantastic.
Next thing Im going to try is scan-doubling CGA / medium res games on a VGA monitor. 30 fps games could get away with a 90fps mode on limited range monitors while 40+ KHz capable monitors should be able to something like 512x448120p quite handily!
Exciting stuff!